Showing posts with label The Arrhenius Equation. Show all posts
Showing posts with label The Arrhenius Equation. Show all posts

Sunday, September 18, 2011

The Arrhenius Expression

The rate constant is only constant for a fixed temperature. It increases exponentially as the temperature increases. Arrhenius came up with the following relationship:

k= A exp -Ea/RT       

This is often shown in logarithmic form so that it is the form of y=mx + c form and a graph of lnk against 1/T can be plotted which has a slope of -Ea/R.

Look at page 123 in The Chemistry Course Companion (Geoff Neuss) and the following Chemguide link is useful.
The Arrhenius Equation