Sunday, September 18, 2011

The Arrhenius Expression

The rate constant is only constant for a fixed temperature. It increases exponentially as the temperature increases. Arrhenius came up with the following relationship:

k= A exp -Ea/RT       

This is often shown in logarithmic form so that it is the form of y=mx + c form and a graph of lnk against 1/T can be plotted which has a slope of -Ea/R.

Look at page 123 in The Chemistry Course Companion (Geoff Neuss) and the following Chemguide link is useful.
The Arrhenius Equation

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